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Thermal degradation of stems of borschtia Sosnovskii modified with monoethanolamine (N→B)- trihydroxyborate

https://doi.org/10.33979/2073-7416-2024-111-1-109-116

Abstract

In the presented work, the process of thermodegradation of unmodified and borazote-modified crushed stems of Sosnovsky's Heracleum by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) was investigated. The general purpose of the study is to determine the decomposition temperature of the main chemical components and the values of mass loss of unmodified and modified crushed stems of Sosnovsky's heracleum to establish the conditions for the production of thermal insulation materials based on modified crushed stems. The concentration of the used modifier was 10%, 30% and 50% of monoethanolamine (N→B) trihydroxyborate (MEATHB). The data obtained allowed us to conclude that the use of 30% and 50% MEATHB modifier reduced the magnitude of mass loss compared to the control samples. Thus, the optimal concentration of the modifier different 30% was established for the manufacture of composites from modified crushed stems of Sosnovsky's heracleum with the possibility of processing and/or drying at temperatures less than 100°C.

About the Authors

I. V. Stepina
National Research Moscow State University of Civil Engineering
Russian Federation

Stepina Irina V.,  Candidate of Technical Sciences, Assoc. Prof., Lecturer of the Department of Building Materials Science,

Moscow.



M. Sodomon
National Research Moscow State University of Civil Engineering
Russian Federation

Sodomon Mark, Postgraduate Student of the Department of Building Materials Science,

Moscow.



A. A. Kruk
National Research Moscow State University of Civil Engineering
Russian Federation

Kruk Artem An., Student of the Department of Building Materials Science,

Moscow.



E. S. Solovyeva
National Research Moscow State University of Civil Engineering
Russian Federation

Solovieva Ekaterina S., Student of the Department of Building Materials Science,

Moscow.



References

1. Vinogradova Y.K., Mayorov S.R., Khorun L.V. Chernaya kniga flory Sredneĭ Rossii (Chuzherodnyye vidy rasteniĭ v ekosistemakh SredneĭRossii) [Black Book of Flora of Middle Russia (Alien plant species in ecosystems of Middle Russia)]. M.: GEOS, 2009. 494 p. (rus)

2. Shestakov D.I., Minakova A.R., Simonova E.I. Issledovaniye vozmozhnosti ispol'zovaniya borshchevika Sosnovskogo kak syr'ya dlya proizvodstva tsellyulozy [Investigation of the possibility of using Sosnovsky's borsch as a raw material for cellulose production]. Materialy XVI Vserossiyskoy nauchno-tekhnicheskoy konferentsii studentov i aspirantov: posvyashchayetsya 90-letiyu Ural'skogo gosudarstvennogo lesotekhnicheskogo universiteta (ULTI UGLTA UGLTU). [Proceedings of the XVI All-Russian Scientific and Technical Conference of Students and Postgraduates: Dedicated to the 90th Anniversary of the Ural State Forestry University]. UGLTU, 2020. Pp. 525-527. (rus)

3. Toturbiev B. D., Mamaev S. A., Toturbiev A. B. Nizkoobzhigovaya, energosberegayushchaya, ekologicheski bezopasnaya tekhnologiya proizvodstva keramicheskikh materialov na osnove glinistykh slantsev [Lowfiring, energy-saving, environmentally safe technology for the production of ceramic materials based on clay shale]. Geology and Geophysics of Southern Russia. 2022. Vol. 12. No 1. Pp. 148-161. (rus)

4. Semenova E.E., Artamonov N.P. Analiz primeneniya sovremennykh energosberegayushchikh materialov pri rekonstruktsii torgovykh tsentrov [Analysis of the application of modern energy-saving materials in the reconstruction of shopping centers]. Engineering systems and facilities. 2016. Vol. 24-25. No 3-4. Pp. 57-60. (rus)

5. Zolotarev A.С. Razrabotka sovremennykh ekologichnykh teploizolyatsionnykh materialov na osnove pererabotki otkhodov rasteniyevodstva [Development of modern environmentally friendly heat-insulating materials based on the processing of crop wastes]. Scientific Journal of Young Scientists. 2022. Vol.30. No 5. Pp. 45-50. (rus)

6. Saprykin N.V. Povysheniye effektivnosti kapital'nogo remonta i rekonstruktsii zdaniy na osnove energosberezheniya [Improving the efficiency of capital repair and reconstruction of buildings on the basis of energy saving]. Scientific Journal of Young Scientists. 2015. Vol. 16. No 3. Pp. 251-255. (rus)

7. Kolosova A.S., Pikalov E.С. Sovremennyye effektivnyye teploizolyatsionnyye materialy na organicheskoy osnove [Modern effective thermal insulation materials on organic basis]. International Journal of Applied and Fundamental Research. 2021. No 4. Pp. 74-85. (rus)

8. Aditya L. et al. A review on insulation materials for energy conservation in buildings. Renewable and sustainable energy reviews. 2017. Vol. 73. Pp. 1352-1365.

9. Cosentino L., Fernandes J., Mateus R. A Review of Natural Bio-Based Insulation Materials //Energies. – 2023. Vol. 16. No 12. Pp. 4676.

10. Smirnova O.E., Ottochko S.Yu. Vozmozhnosti izgotovleniya teploizolyatsionnykh materialov na osnove organicheskikh otkhodov [Possibilities of manufacturing of thermal insulation materials based on organic waste]. Proceedings of the Novosibirsk State University of Architecture and Civil Engineering (Sibstrin). 2017. Vol. 20. No 2. Pp. 120-130. (rus)

11. Shabalina O.N., Gorbushina T.N., Gordina A.F. Razrabotka teploizolyatsionnogo materiala s primeneniyem kostry l'na [Development of thermal insulation material with the use of flax bark]. Molodyye uchenyyeuskoreniyu nauchno-tekhnicheskogo progressa v XXI veke. [Proceedings of the IV All-Russian Scientific and Technical Conference of Postgraduate Students, Masters Students and Young Scientists with International Participation (Young Scientists - Acceleration of Scientific and Technical Progress in the XXI Century)]. Izhevsk : Izd-vo INNOVA, 2016. Pp. 864-868. (rus)

12. Sodomon M., Stepina I.V. Teplofizicheskie svojstva kompozitnogo materiala na osnove rastitel'nogo syr'ya [Thermophysical properties of composite material based on plant raw materials]. Silicate engineering and technology. 2022. Vol. 29. No 4. Pp. 342-349. (rus).

13. Koteneva I.V. Borazotnyye modifikatory dlya zashchity drevesiny stroitel'nykh konstruktsiy. [Borazotnye modifiers for wood protection of building structures]. Moscow : MSCU, 2011. 191p. (rus)

14. Yang H. et al. Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel. 2007. Vol. 86. No 12-13. Pp. 1781-1788.

15. Poletto M., Júnior H.L.O., Zattera A.J. Thermal decomposition of natural fibers: kinetics and degradation mechanisms. Reactions and mechanisms in thermal analysis of advanced materials. 2015. Pp. 515-545.

16. Mikova N.M., Fetisova O.Yu., Pavlenko N.I., Chesnokov N.V. Izucheniye termicheskogo povedeniya organosol'ventnykh ligninov, vydelennykh iz drevesiny pikhty i osiny [Study of thermal behavior of organosolvent lignins isolated from fir and aspen wood]. Chemistry for sustainable development. 2018. Vol. 26. No 4. Pp. 411-418. (rus)

17. Destaing F. Contribution à l’étude du comportement mécanique de matériaux composites biosourcés lin/PA11 élaborés par thermocompression : Diss. – Caen, 2012. (French).

18. Malyar Yu. N. et al. Izucheniye organosol'ventnykh ligninov s metodami gel'-pronikayushchey khromatografii i termicheskogo analiza [Study of organo-solvent lignins using gel permeation chromatography and thermal analysis]. Journal of the Siberian Federal University. Chemistry. 2019. Vol. 12. Vol. 1. Pp. 73-86. (rus)

19. Stepina I.V., Sodomon M., Kononov G.N., Petukhov V.A. Komponentnyy sostav modifitsirovannogo rastitel'nogo syr'ya [Component composition of modified plant raw materials]. Don Engineering Bulletin. 2022. Vol. 93. No 9. Pp. 223-231.


Review

For citations:


Stepina I.V., Sodomon M., Kruk A.A., Solovyeva E.S. Thermal degradation of stems of borschtia Sosnovskii modified with monoethanolamine (N→B)- trihydroxyborate. Building and Reconstruction. 2024;(1):109-116. (In Russ.) https://doi.org/10.33979/2073-7416-2024-111-1-109-116

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